Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal
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چکیده
منابع مشابه
Dansyl - Substituted Aza Crown Ethers: Complexation with Alkali, Alkaline Earth Metal Ions and Ammonium.
The present study investigates the binding properties of four dansyl substituted aza-crown ethers with alkali, alkaline earth metal ions and ammonium. The influence of the solvent polarity and protonation on the photophysical properties of the compounds was studied by UV/Vis and fluorescence methods. The host species caused only slight changes on the absorption spectra of the ligands. The fluor...
متن کاملNew "off-on" responsible fluoroionophores for alkaline earth metal ions based on benzo-15-crown-5 bearing 9-phenanthreneacetamide.
The photochemical behaviors of a series of 9-phenanthreneacetamide (PA) derivatives were investigated using UV, fluorescence, and (1)H-NMR spectroscopy in acetonitrile solutions. To apply the electron transfer (ET) action of PA as a detecting moiety of chemosensors, 4'-(9-phenanthreneacetamido)-benzo-15-crown-5 (1) and 3'-methyl-4'-(9-phenanthreneacetamido)-benzo-15-crown-5 (2) were synthesized...
متن کاملNMR Study of Benzo-15-Crown-5 Complexes with 7Li+ and 133Cs+ Ions in Nonaqueous solvents
Complexes of benzo-15-crown-5 macrocycle with Li+ and Cs+ ions were investigated by 7Li and 133Cs NMr in a number of nonoqueous solutions. The resulting 1:1 complex with Li+ ion was found to be much more stable than that with Cs+ ion. With the exception of pyridine solutions the stabilities of the complexes varied inversely w...
متن کاملA structural study of alkaline earth metal complexes with hybrid disila - crown ethers † Fabian Dankert
Compounds consisting of [M(1,2-disila-[3n]crown-n)] (M = Mg, Ca, Sr, Ba; n = 5, 6) and [Ba(1,2-disilabenzo[18]crown-6)] cations and different anions were obtained by equimolar reaction of the hybrid disila-crown ethers 1,2-disila[15]crown-5 (1), 1,2-disila[18]crown-6 (2) and 1,2-disila-benzo[18]crown-6 (7) with alkaline earth metal salts. Even with strongly coordinating anions such as Br or I s...
متن کاملA structural study of alkaline earth metal complexes with hybrid disila-crown ethers.
Compounds consisting of [M(1,2-disila-[3n]crown-n)]2+ (M = Mg, Ca, Sr, Ba; n = 5, 6) and [Ba(1,2-disila-benzo[18]crown-6)]2+ cations and different anions were obtained by equimolar reaction of the hybrid disila-crown ethers 1,2-disila[15]crown-5 (1), 1,2-disila[18]crown-6 (2) and 1,2-disila-benzo[18]crown-6 (7) with alkaline earth metal salts. Even with strongly coordinating anions such as Br- ...
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ژورنال
عنوان ژورنال: Journal of Zhejiang University SCIENCE
سال: 2005
ISSN: 1009-3095
DOI: 10.1631/jzus.2005.b0069